The cadmium sulphide sensitized photo-oxidation of Leuco Crystal Violet in oxygenated MeCN occurs initially by an electron transfer mechanism until superoxide anion concentration increases sufficiently to compete by a hydrogen atom abstraction process.
F. D. Saeva, G. R. Olin and J. R. Harbour, J. Chem. Soc., Chem. Commun., 1978, 417 DOI: 10.1039/C39780000417
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