The concept that water contains an equilibrium concentration of ‘free’ OH and ‘free’ lone-pair groups is used to give a qualitative explanation of the large rate changes observed for certain hydrolyses on the addition of cosolvents.
M. C. R. Symons, J. Chem. Soc., Chem. Commun., 1978, 418 DOI: 10.1039/C39780000418
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