Issue 12, 1978
From the journal:

Journal of the Chemical Society, Dalton Transactions

Bis(styrene)bis(triphenylphosphine)ruthenium(0) and its reactions with triphenylphosphine and with alkenes

Bruno N. Chaudret,   David J. Cole-Hamilton  and  Geoffrey Wilkinson  

Abstract

A complex previously thought to be styrenetris(triphenylphosphine)ruthenium(0) is shown to be bis(styrene)bis-(triphenylphosphine)ruthenium(0). The complex appears to react with aliphatic and aromatic hydrocarbons to form dihydridotetrakis(triphenyIphosphine)ruthenium(II), RuH2(PPh3)4, but the source of the hydride is shown to be triphenylphosphine.

The reactions of the complex with ethylene and other aikenes have been studied and the products characterised by analysis, i.r., and 1H and 31P n.m.r. spectra.

New complexes described are: Ru(C2H4)2(C8H8)(PPh3)2, Ru(C4H6)(C8H8)(PPh3)2, Ru(C4H6)2(PPh3)2, RuH(C6H11)(C8H8)(PPh3)2 and Ru(C6H10)(C8H8)(PPh3)2.

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Article information

DOI
https://doi.org/10.1039/DT9780001739
Article type
Paper

J. Chem. Soc., Dalton Trans., 1978, 1739-1745

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Bis(styrene)bis(triphenylphosphine)ruthenium(0) and its reactions with triphenylphosphine and with alkenes

B. N. Chaudret, D. J. Cole-Hamilton and G. Wilkinson, J. Chem. Soc., Dalton Trans., 1978, 1739 DOI: 10.1039/DT9780001739

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