Studies of competition between substitution and chlorine abstraction reactions of photochemically generated ·Re(CO)5 radicals show that substitution proceeds via a second-order associative path and not via CO dissociation.
A. Fox, J. Malito and A. Poë, J. Chem. Soc., Chem. Commun., 1981, 1052 DOI: 10.1039/C39810001052
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