The molecular structure of the novel compound [1,1,2-(CO)3-1-(PPh3)-2,2-(Ph2P-ortho-[graphic omitted]4H2)], isolated as an advanced degradation product from the reaction of closoB-10H102– with trans-[Ir(CO)Cl(PPh3)2] in methanolic solution, is based on a closed {Ir2B4} octahedral cluster with the metal atoms occupying adjacent vertices.
J. E. Crook, N. N. Greenwood, J. D. Kennedy and W. S. McDonald, J. Chem. Soc., Chem. Commun., 1982, 383 DOI: 10.1039/C39820000383
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