Isomeric ethoxycarbonyl-substituted but-3-enyl- and cyclopropylmethyl-(pyridine)cobaloximes undergo trifluoroacetic acid-catalysed equilibration; the significance of this and other observations for the mechanism of B12-dependent α-methyleneglutarate mutase is discussed.
B. T. Golding and S. Mwesigye-Kibende, J. Chem. Soc., Chem. Commun., 1983, 1103 DOI: 10.1039/C39830001103
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