Intramolecular addition of a α-sulphinyl carbanion to an isolated double bond is observed with mesocyclic metallated E homoallylic sulphoxides (1) and (2); kinetic data suggest that this process is acid catalysed and that free (1) is the proton donor species.
V. Cerè, C. Paolucci, S. Pollicino, E. Sandri and A. Fava, J. Chem. Soc., Chem. Commun., 1986, 223 DOI: 10.1039/C39860000223
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