The Se4l42+ cation has been prepared by the reaction of Se42+ and iodine in SO2 solution; the 77Se n.m.r. spectrum is consistent with an I2Se+SeSeSe+I2 structure for the cation, and the equilibrium of Se4I42+ with lesser amounts of SeI3+ and Se6I22+.
M. M. Carnell, F. Grein, M. Murchie, J. Passmore and C. Wong, J. Chem. Soc., Chem. Commun., 1986, 225 DOI: 10.1039/C39860000225
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