The cycloaddition–fragmentation mechanism proposed for the reaction of 1,3-diaryltriazenes with tetracyanoethylene is ruled out by a tracer experiment using a 15N labelled triazene, which strongly supports the intermediacy of an arylazomalononitrile.
T. Mitsuhashi, C. Matsumura and Y. Koga, J. Chem. Soc., Chem. Commun., 1986, 257 DOI: 10.1039/C39860000257
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