The magnetically unique diastereoisomers of tetra- and hexa-alditol peracetates can be correctly identified by comparing the observed vicinal (backbone) H–H coupling constants with those calculated by molecular mechanics and a generalized Karplus equation.
S. Masamune, P. Ma, R. E. Moore, T. Fujiyoshi, C. Jaime and E. Ōsawa, J. Chem. Soc., Chem. Commun., 1986, 261 DOI: 10.1039/C39860000261
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