Issue 3, 1986

Rate enhancements and secondary β-deuterium kinetic isotope effects as criteria of neighbouring group participation. Solvolysis of some tertiary alk-5-enyl chlorides

Abstract

Rate enhancements in solvolysis of several of the title compounds are small or zero but significantly reduced secondary β-deuterium kinetic isotope effects indicate participation of the double bond.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 263-264

Rate enhancements and secondary β-deuterium kinetic isotope effects as criteria of neighbouring group participation. Solvolysis of some tertiary alk-5-enyl chlorides

M. Orlović, K. Humski, S. Borčić and E. Polla, J. Chem. Soc., Chem. Commun., 1986, 263 DOI: 10.1039/C39860000263

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