A methoxyhydroperoxide analogue (12) to a proposed aromatase intermediate has been synthesized by ozonolysis of methoxyvinyl compound (7) in the presence of methanol; it has been shown not to produce estrone with or without acetylation, but the free hydroperoxide apparently undergoes a facile, stereospecific intramolecular epoxidation.
P. A. Cole and C. H. Robinson, J. Chem. Soc., Chem. Commun., 1986, 1651 DOI: 10.1039/C39860001651
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