Structures of the ribose-methylated nucleosides 5,2′-O-dimethylcytidine (1), N4-acetyl-2′-O-methylcytidine (2), 2-thio-2′-O-methyluridine (3), and N2,N2,2′-O-trimethylguanosine (4) from the transfer RNA of Sulfolobus solfataricus, Thermoproteus neutrophilus, and Pyrodictium occultum have been established, and verified by chemical synthesis.
C. G. Edmonds, P. F. Crain, T. Hashizume, R. Gupta, K. O. Stetter and J. A. McCloskey, J. Chem. Soc., Chem. Commun., 1987, 909 DOI: 10.1039/C39870000909
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