The synthesis and structure of {Ag5[µ2-S–(CH2)3–NHMe2]3[µ2-S–(CH2)3–NMe2]3}(ClO4)2; the Ag5S6 core of the cage cation provides the only known case of an [Mx(SR)y] aggregate that can be described as a trigonal bipyramid of metal atoms enclosed within a regular trigonal prism of doubly bridging thiolate ligands.
P. González-Duarte, J. Sola, J. Vives and X. Solans, J. Chem. Soc., Chem. Commun., 1987, 1641 DOI: 10.1039/C39870001641
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