Selectivities for ethene and ethane formation during oxidative dimerization of methane over cerium mixed oxide catalysts Ce1 –x Ybx02 – 0.5x and SrCe1 –x YbxO3 – 0.5 x appear to be related to the nature of their ionic conduction, decreasing with oxygen ion mobility while increasing with proton mobility.
K. Machida and M. Enyo, J. Chem. Soc., Chem. Commun., 1987, 1639 DOI: 10.1039/C39870001639
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