A synthetic strategy based upon the use of thioglycosides to generate 1,2-trans-glycosidic linkages has been developed and has permitted efficient synthesis of pentameric α-1,2 linked 4,6-dideoxy-4-formamido-α-D-mannose homo-oligomers as well as structures containing α-1,3 linkages.
T. Peters and D. R. Bundle, J. Chem. Soc., Chem. Commun., 1987, 1648 DOI: 10.1039/C39870001648
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