Issue 21, 1987

Quantitative thermal rearrangement of an eleven-vertex metalladicarbaborane to give the isomeric cluster nido-[2-(η6-C6Me6)-8,10-Me2-2,8,10-OsC2B8H8] with an unexpected BCBCB open face

Abstract

The molecular structure of the title compound exhibits a five-membered [graphic omitted] open face and is thereby fundamentally different from the closo-nature previously assumed and generally accepted for this type of polyhedral metalladicarbaborane cluster compound.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1650-1651

Quantitative thermal rearrangement of an eleven-vertex metalladicarbaborane to give the isomeric cluster nido-[2-(η6-C6Me6)-8,10-Me2-2,8,10-OsC2B8H8] with an unexpected BCBCB open face

M. Bown, X. L. R. Fontaine, N. N. Greenwood, J. D. Kennedy and M. Thornton-Pett, J. Chem. Soc., Chem. Commun., 1987, 1650 DOI: 10.1039/C39870001650

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