O,O-Dimethylkorupensamine A was stereoselectively synthesized by using the palladium(0)-mediated cross-coupling of the enantiomerically pure tricarbonylchromium complex of 3,5-dimethoxy-2-bromobenzene having a functional group at C-1 position with naphthylboronic acid as a key step.
T. Watanabe and M. Uemura, Chem. Commun., 1998, 871 DOI: 10.1039/A800075A
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