Dimeric ortho-phenyleneindium bromide 1 shows a higher affinity for 1,2-diazines than for 1,3- and 1,4-diazines; as shown by the X-ray crystal structure analysis of the host–guest complex 3 the observed selectivity results from subtle structural variation which can bring the indium p orbitals to converge.
F. P. Gabbaï, A. Schier, J. Riede, A. Schier and M. J. Hynes, Chem. Commun., 1998, 897 DOI: 10.1039/A800413G
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