A combination of experiment and theory has identified both the allyltin trichlorides 3 (R2 = Bn, H) as key intermediates in tin(IV) chloride-promoted reactions of allylstannanes 1 (R2 = Bn, H) and the transition structures that are involved in their reactions with aldehydes.
L. A. Hobson, M. A. Vincent and E. J. Thomas, Chem. Commun., 1998, 899 DOI: 10.1039/A800781K
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