A search of the Cambridge Structural Database reveals that the methylene group of coordinated bis(diphenylphosphino)methane and related ligands can act as a hydrogen bond donor, with H···O distances as short as 2.20 Å; analogous C–H···Cl– interactions are a feature of the packing of dppmSe complexes of silver(I) and gold(I).
P. G. Jones and B. Ahrens, Chem. Commun., 1998, 2307 DOI: 10.1039/A803905D
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