An analysis of a thermodynamic cycle for the formation of ligand-bound dimers gives a simple illustration as to how a cooperative binding energy (ΔG°coop) can be expressed over a range of interfaces, rather than at just one of the interfaces within the array.
B. Bardsley and D. H. Williams, Chem. Commun., 1998, 2305 DOI: 10.1039/A806774K
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