Control of proton transfer by hydrogen bonding in the protonated forms of the binucleophilic complex [{η5-C5H4CH(CH2)4NMe}Ir(PPh3)H2]
Abstract
Proton transfer reactions between both nucleophilic sites of a dihydrido iridium complex containing the 4-N-methylpiperidylcyclopentadienyl ligand and their dependance with the hydrogen bonding ability of the solvent medium are studied by NMR.