New halide-substituted cluster anions [Cd10S4X4(SR)12]4– (R=Ph, X = I, 2a; R = p-MeC6H4, X = I, 3a or Br, 3b) of the [Cd10S4(SR)16]4– family have been prepared and characterized; investigations of their luminescence show that the introduction of the halide groups produces red shifts and significant enhancements in their emission intensities.
R. D. Adams, B. Zhang, C. J. Murphy and L. K. Yeung, Chem. Commun., 1999, 383 DOI: 10.1039/A809443H
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