Issue 8, 2000
From the journal:

Chemical Communications

Fluoridation of heteroaromatic iodonium salts—experimental evidence supporting theoretical prediction of the selectivity of the processElectronic supplementary information (ESI) available: typical experimental and coordinate files for on line viewing of the transition state models. See http://www.rsc.org/suppdata/cc/b0/b000868k/

Sonsoles Martín-Santamaría,a   Michael A. Carroll,‡a   Colm M. Carroll,‡a   Charles D. Carter,‡a   Victor W. Pike,b   Henry S. Rzepa*a  and  David A. Widdowson*a  

* Corresponding authors

a Department of Chemistry, Imperial College of Science, Technology and Medicine, London, UK
E-mail: d.widdowson@ic.ac.uk, h.rezpa@ic.ac.uk

b Chemistry and Engineering Group, MRC Cyclotron Unit, Imperial College School of Medicine, Hammersmith Hospital, Ducane Road, London, UK

Abstract

Theoretical prediction, that the nucleophilic substitution of a range of arylheteroaryliodonium salts by fluoride ion is regioselective for the aryl ring with the exception of benzo[b]furan, are borne out by experimental observation.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B000868K
Article type
Communication
Submitted
01 Feb 2000
Accepted
01 Mar 2000
First published
27 Mar 2000

Chem. Commun., 2000, 649-650

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Fluoridation of heteroaromatic iodonium salts—experimental evidence supporting theoretical prediction of the selectivity of the process

S. Martín-Santamaría, M. A. Carroll, C. M. Carroll, C. D. Carter, V. W. Pike, H. S. Rzepa and D. A. Widdowson, Chem. Commun., 2000, 649 DOI: 10.1039/B000868K

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