Issue 14, 2000
From the journal:

Chemical Communications

Rhodium(i) complexes of unsymmetrical diphosphines: efficient and stable methanolcarbonylation catalystsElectronic supplementary information (ESI) available: typical experimental procedure for catalysis. See http://www.rsc.org/suppdata/cc/b0/b002802i/

Charles-Antoine Carraz,a   Evert J. Ditzel,b   A. Guy Orpen,a   Dianne D. Ellis,a   Paul G. Pringle*a  and  Glenn J. Sunleyb  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantocks Close, Bristol, UK
E-mail: paul.pringle@bristol.ac.uk

b BP Chemicals, Hull Research and Technology Centre, Saltend, Hull, UK

Abstract

Rhodium complexes of unsymmetrical diphosphines of the type Ph2PCH2CH2PAr2 are catalysts for the carbonylation of methanol; several features of the catalysis are reminiscent of iridium carbonylation catalysts.

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Article information

DOI
https://doi.org/10.1039/B002802I
Article type
Communication
Submitted
07 Apr 2000
Accepted
17 May 2000
First published
28 Jun 2000

Chem. Commun., 2000, 1277-1278

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Rhodium(I) complexes of unsymmetrical diphosphines: efficient and stable methanol carbonylation catalysts

C. Carraz, E. J. Ditzel, A. G. Orpen, D. D. Ellis, P. G. Pringle and G. J. Sunley, Chem. Commun., 2000, 1277 DOI: 10.1039/B002802I

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