A three-dimensional neutral framework of a novel decavanadium cluster bridged by an AsO4 tetrahedron: [AsVIV8VV2O26(μ-H2O)]·8H2O

Wei-Ming Bu; Ling Ye; Guo-Yu Yang; Mei-Cheng Shao; Yu-Guo Fan; Ji-Qing Xu

doi:10.1039/B003359F

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A three-dimensional neutral framework of a novel decavanadium cluster bridged by an AsO₄ tetrahedron: [AsV^IV₈V^V₂O₂₆(μ- H₂O)]·8H₂O

Wei-Ming Bu,^a Ling Ye,^a Guo-Yu Yang,^b Mei-Cheng Shao,^c Yu-Guo Fan*^a and Ji-Qing Xu^a

Author affiliations

* Corresponding authors

^a Key Lab of Supramolecular Structure and Spectroscopy, Jilin University, Changchun, P.R. China.
E-mail: xray@mail.jlu.edu.cn

^b Department of Chemistry of Biochemistry, University of Notre Dame, IN, USA

^c Department of Chemistry, Peking University, Beijing 1, P.R. China

Abstract

A three-dimensional neutral framework of a novel decavanadate ion [V^IV₈V^V₂O₂₆(μ-H ₂O)] containing an AsO₄ tetrahedral bridge has been synthesized hydrothermally and structurally characterized by X-ray diffraction.

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Supplementary files

Crystal structure data TXT (14K)

Article information

DOI: https://doi.org/10.1039/B003359F
Article type: Communication
Submitted: 26 Apr 2000
Accepted: 02 Jun 2000
First published: 29 Jun 2000

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Chem. Commun., 2000, 1279-1280

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A three-dimensional neutral framework of a novel decavanadium cluster bridged by an AsO₄ tetrahedron: [AsV^IV₈V^V₂O₂₆(μ- H₂O)]·8H₂O

W. Bu, L. Ye, G. Yang, M. Shao, Y. Fan and J. Xu, Chem. Commun., 2000, 1279 DOI: 10.1039/B003359F

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