Issue 2, 2001
From the journal:

Chemical Communications

A Pd complex of a tridentate pincer CNC bis-carbene ligand as a robust homogenous Heck catalystElectronic supplementary information (ESI) available: synthesis details and NMR data. See http://www.rsc.org/suppdata/cc/b0/b008038l/

Eduardo Peris,*a   Jennifer A. Loch,b   José Mataa  and  Robert H. Crabtree*b  

* Corresponding authors

a Dpto. de Química Inorgánica y Orgánica, Universitat Jaume I, Castellón, Spain.
E-mail: eperis@vents.uji.es

b Department of Chemistry, Yale University, P.O. Box 208107, New Haven, CT, USA.
E-mail: robert.crabtree@yale.edu

Abstract

The bis-carbene precursor, 1, gives a thermally very robust Pd(II) catalyst for Heck coupling that maintains activity even in boiling diethylacetamide (bp 184 °C) in air.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B008038L
Article type
Communication
Submitted
02 Oct 2000
Accepted
06 Dec 2000
First published
16 Jan 2001

Chem. Commun., 2001, 201-202

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A Pd complex of a tridentate pincer CNC bis-carbene ligand as a robust homogenous Heck catalyst

E. Peris, J. A. Loch, J. Mata and R. H. Crabtree, Chem. Commun., 2001, 201 DOI: 10.1039/B008038L

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