Issue 2, 2001
From the journal:

Chemical Communications

A novel chemiluminescence from the reaction of dioxiranes with

Dmitri V. Kazakov,*a   Anna B. Barzilovaa  and  Valeri P. Kazakova  

* Corresponding authors

a Institute of Organic Chemistry, Ufa Scientific Center of the RAS, 71 Pr. Oktyabrya, Ufa, Russia.
E-mail: chemlum@ufanet.ru

Abstract

Oxidation of adamantane and 2,3-dimethylbutane by methyl(trifluoromethyl)dioxirane is accompanied by chemiluminescence (CL); formation of the emitter of CL, triplet excited trifluoropropanone, is proposed to occur via a concerted oxenoid mechanism of oxygen insertion into C–H bond of the hydrocarbons.

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Article information

DOI
https://doi.org/10.1039/B008315L
Article type
Communication
Submitted
16 Oct 2000
Accepted
07 Dec 2000
First published
08 Jan 2001

Chem. Commun., 2001, 191-192

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A novel chemiluminescence from the reaction of dioxiranes with alkanes. Proposed mechanism of oxygen-transfer chemiluminescence

D. V. Kazakov, A. B. Barzilova and V. P. Kazakov, Chem. Commun., 2001, 191 DOI: 10.1039/B008315L

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