Glycosyldisulfides: a new class of solution and solid phase glycosyl donorsElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b0/b008734n/Some of this work was presented at a joint meeting of the RSC Carbohydrate and Bioorganic groups, Warwick, July 6 2000 and at the 20th International Carbohydrate Symposium, Hamburg, August 30, 2000.

Abstract

Mixed glycosyl disulfides are not only glycomimetics but also glycosyl donors that may be readily constructed in either armed ether-protected or disarmed ester-protected and in soluble or solid-supported forms from corresponding glycosyl methanethiosulfonates and used in the glycosylation of a variety of representative acceptors.