Toward constructing nanoscale hydroxo–lanthanide clusters: syntheses and characterizations of novel tetradecanuclear hydroxo–lanthanide clusters
Abstract
Two novel tetradecanuclear hydroxo–lanthanide complexes, formulated as Ln14(μ4-OH)2(μ3-OH)16(μ-η2-acac)8(η2-acac)16, Ln = Tb, 1; Eu, 2; acac = acetylacetonato, were synthesized and characterized by