Zipping up ‘the crushed fullerene’ C60H30: C60 by fifteen-fold, consecutive intramolecular H2 losses

Berta Gómez-Lor; Carola Koper; Roel H. Fokkens; Edward J. Vlietstra; Thomas J. Cleij; Leonardus W. Jenneskens; Nico M. M. Nibbering; Antonio M. Echavarren

doi:10.1039/B110587F

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Zipping up ‘the crushed fullerene’ C₆₀H₃₀: C₆₀ by fifteen-fold, consecutive intramolecular H₂ losses†

Berta Gómez-Lor,^ab Carola Koper,^c Roel H. Fokkens,^d Edward J. Vlietstra,^c Thomas J. Cleij,^c Leonardus W. Jenneskens,*^c Nico M. M. Nibbering^e and Antonio M. Echavarren^a

Author affiliations

* Corresponding authors

^a Departamento de Quimica Orgánica, Universidad Autónoma de Madrid, Cantoblanco, Madrid, Spain

^b Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, Madrid, Spain

^c Debye Institute, Department of Physical Organic Chemistry, Utrecht University, Padualaan 8, CH Utrecht, The Netherlands
E-mail: jennesk@chem.uu.nl

^d Supramolecular Chemistry and Technology, MESA+ Research Institute, University of Twente, P.O. Box 217, AE Enschede, The Netherlands

^e Laser Centre and Chemistry Department, Vrije Universiteit, De Boelelaan 1083, Amsterdam, The Netherlands

Abstract

MALDI TOF-MS of tribenzo[l∶l′∶l″]benzo[1,2-e∶3,4-e′∶5,6-e″]triacephenanthrylene (1a, C₆₀H₃₀) gives C₆₀^.+ by multiple intramolecular cyclodehydrogenation reactions.

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Supplementary files

AM1 optimised geometries, heats of formation, first ionisation potentials, Schlegel diagrams and MALDI TOF-MS spectrum of 1a DOC (1149K)

Article information

DOI: https://doi.org/10.1039/B110587F
Article type: Communication
Submitted: 19 Nov 2001
Accepted: 14 Jan 2002
First published: 30 Jan 2002

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Chem. Commun., 2002, 370-371

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Zipping up ‘the crushed fullerene’ C₆₀H₃₀: C₆₀ by fifteen-fold, consecutive intramolecular H₂ losses

B. Gómez-Lor, C. Koper, R. H. Fokkens, E. J. Vlietstra, T. J. Cleij, L. W. Jenneskens, N. M. M. Nibbering and A. M. Echavarren, Chem. Commun., 2002, 370 DOI: 10.1039/B110587F

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