Issue 4, 2002

Synthesis of the RuIV amido complex [TpRu(CO)(PPh3)(NHPh)][OTf]2 (Tp = hydridotris(pyrazolyl)borate; OTf = trifluoromethanesulfonate) and deprotonation to form an octahedral and d4 imido complex: computational study of RuIV–imido bonding

Abstract

Deprotonation of [TpRu(CO)(PPh3)(NHPh)][OTf]2 yields the thermally unstable d4 imido complex [TpRu(CO)(PPh3)(NPh)][OTf]; a computational study of the bonding of the imido complex provides a foundation for discussion of its instability in terms of π-conflict.

Graphical abstract: Synthesis of the RuIV amido complex [TpRu(CO)(PPh3)(NHPh)][OTf]2 (Tp = hydridotris(pyrazolyl)borate; OTf = trifluoromethanesulfonate) and deprotonation to form an octahedral and d4 imido complex: computational study of RuIV–imido bonding

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
04 Dec 2001
Accepted
09 Jan 2002
First published
29 Jan 2002

Chem. Commun., 2002, 372-373

Synthesis of the RuIV amido complex [TpRu(CO)(PPh3)(NHPh)][OTf]2 (Tp = hydridotris(pyrazolyl)borate; OTf = trifluoromethanesulfonate) and deprotonation to form an octahedral and d4 imido complex: computational study of RuIV–imido bonding

K. N. Jayaprakash, A. M. Gillepsie, T. B. Gunnoe and D. P. White, Chem. Commun., 2002, 372 DOI: 10.1039/B110999E

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