Issue 2, 2003
From the journal:

Chemical Communications

Further reactions of phenyldimethylsilyllithium with N,N-dimethylamides

Ian Fleming*a  and  Matthew G. Russella  

* Corresponding authors

a Department of Chemistry, Lensfield Road, Cambridge, UK
E-mail: if10000@cam.ac.uk
Fax: 44 1223 336362
Tel: 44 1223 336372

Abstract

Phenyldimethylsilyllithium reacts with several N,N-dimethylamides, and the intermediates, formulated here as successively a carbene and an α-silyllithium species, may be trapped with nucleophiles and electrophiles, respectively, although not always with the nucleophile or electrophile of your choice.

Graphical abstract: Further reactions of phenyldimethylsilyllithium with N,N-dimethylamides

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Article information

DOI
https://doi.org/10.1039/B210442C
Article type
Communication
Submitted
29 Oct 2002
Accepted
09 Dec 2002
First published
17 Dec 2002

Chem. Commun., 2003, 198-199

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Further reactions of phenyldimethylsilyllithium with N,N-dimethylamides

I. Fleming and M. G. Russell, Chem. Commun., 2003, 198 DOI: 10.1039/B210442C

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