Issue 4, 2005
From the journal:

Chemical Communications

Carboxylation of anisole derivatives with CO and O2 catalyzed by Pd(OAc)2 and molybdovanadophosphates

Shinichiro Ohashi,a   Satoshi Sakaguchia  and  Yasutaka Ishii*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering & High Technology Research Center, Kansai University, Suita, Osaka, Japan
E-mail: ishii@ipcku.kansai-u.ac.jp

Abstract

Anisole and its homologues were carboxylated under the influence of CO and O2 catalyzed by Pd(OAc)2 combined with molybdovanadophosphates (HPMoV) under mild conditions to give the corresponding carboxylic acids in fair to good yields; for instance, anisole underwent the carboxylation under a mixed gas of CO (0.5 atm) and O2 (0.5 atm) in the presence of Pd(OAc)2 (5 mol%) and H5PMo10V2O40·nH2O (2 mol%) to form an isomeric mixture of anisic acids in good yield.

Graphical abstract: Carboxylation of anisole derivatives with CO and O2 catalyzed by Pd(OAc)2 and molybdovanadophosphates

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Article information

DOI
https://doi.org/10.1039/B411934G
Article type
Communication
Submitted
03 Aug 2004
Accepted
11 Oct 2004
First published
02 Dec 2004

Chem. Commun., 2005, 486-488

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Carboxylation of anisole derivatives with CO and O2 catalyzed by Pd(OAc)2 and molybdovanadophosphates

S. Ohashi, S. Sakaguchi and Y. Ishii, Chem. Commun., 2005, 486 DOI: 10.1039/B411934G

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