Issue 4, 2005

Reversible 1,4-cycloaddition of singlet oxygen to N-substituted 2-pyridones: 1,4-endoperoxide as a versatile chemical source of singlet oxygen

Abstract

N-substituted pyridones (1) easily undergo singlet oxygenation to give exclusively the corresponding endoperoxides (2), which decompose to give pyridones again while liberating 1O2 in high yield.

Graphical abstract: Reversible 1,4-cycloaddition of singlet oxygen to N-substituted 2-pyridones: 1,4-endoperoxide as a versatile chemical source of singlet oxygen

Supplementary files

Article information

Article type
Communication
Submitted
27 Sep 2004
Accepted
22 Oct 2004
First published
02 Dec 2004

Chem. Commun., 2005, 483-485

Reversible 1,4-cycloaddition of singlet oxygen to N-substituted 2-pyridones: 1,4-endoperoxide as a versatile chemical source of singlet oxygen

M. Matsumoto, M. Yamada and N. Watanabe, Chem. Commun., 2005, 483 DOI: 10.1039/B414845B

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