Issue 30, 2005
From the journal:

Chemical Communications

Novel catalytic effects in esteraminolysis in chlorobenzene†

Nuno Basilio,a   Luís García-Río,*a   J. Ramón Leis,a   Juan C. Mejutob  and  Moisés Pérez-Lorenzoa  

* Corresponding authors

a Dpto. Química Física, Facultade de Química, Universidade de Santiago de Compostela. Avda. das Ciencias s/n, 15782 Santiago de Compostela, Spain
E-mail: qflgr3cn@usc.es
Fax: +34 981 595 012
Tel: +34 981 563 100 Ext. 14280

b Dpto. Química Física, Facultade de Ciencias, Universidade de Vigo., 32004 Ourense, Spain
E-mail: xmejuto@uvigo.es
Tel: +34 988 387 031

Abstract

The mechanism of glyme catalyzed ester aminolysis in chlorobenzene should be modified by including a new reaction pathway that shows a first-order dependence on the concentration of the phase transfer catalyst and a second-order dependence on butylamine.

Graphical abstract: Novel catalytic effects in ester aminolysis in chlorobenzene

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Article information

DOI
https://doi.org/10.1039/B504629G
Article type
Communication
Submitted
04 Apr 2005
Accepted
03 Jun 2005
First published
01 Jul 2005

Chem. Commun., 2005, 3817-3819

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Novel catalytic effects in ester aminolysis in chlorobenzene

N. Basilio, L. García-Río, J. R. Leis, J. C. Mejuto and M. Pérez-Lorenzo, Chem. Commun., 2005, 3817 DOI: 10.1039/B504629G

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