Issue 30, 2005
From the journal:

Chemical Communications

Formation of a long-lived charge-separated state of a zinc phthalocyanine-perylenediimide dyad by complexation with magnesium ion†

Shunichi Fukuzumi,*a   Kei Ohkubo,a   Javier Ortiz,b   Ana M. Gutiérrez,b   Fernando Fernández-Lázaro*b  and  Ángela Sastre-Santos*b  

* Corresponding authors

a Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST, Japan Science and Technology Agency (JST), Suita, Osaka, Japan
E-mail: fukuzumi@chem.eng.osaka-u.ac.jp
Fax: +81-6-6879-7370
Tel: +81-6-6879-7368

b División de Química Orgánica Instituto de Bioingeniería, Universidad Miguel Hernández, Elche, Spain
E-mail: fdofdez@umh.es, asastre@umh.es

Abstract

Photoexcitation of a zinc phthalocyanine–perylenediimide (ZnPc–PDI) dyad affords the triplet excited state without the fluorescence emission, whereas addition of Mg2+ to the photoexcited ZnPc–PDI results in formation of a long-lived charge-separated state (ZnPc˙+–PDI˙−/Mg2+) in which PDI˙− forms a complex with Mg2+.

Graphical abstract: Formation of a long-lived charge-separated state of a zinc phthalocyanine-perylenediimide dyad by complexation with magnesium ion

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B506412K
Article type
Communication
Submitted
09 May 2005
Accepted
01 Jun 2005
First published
28 Jun 2005

Chem. Commun., 2005, 3814-3816

Permissions

Request permissions

Formation of a long-lived charge-separated state of a zinc phthalocyanine-perylenediimide dyad by complexation with magnesium ion

S. Fukuzumi, K. Ohkubo, J. Ortiz, A. M. Gutiérrez, F. Fernández-Lázaro and Á. Sastre-Santos, Chem. Commun., 2005, 3814 DOI: 10.1039/B506412K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements