Issue 30, 2005
From the journal:

Chemical Communications

A new synthetic route to bulky “second generation” tris(imidazol-2-ylidene)borate ligands: synthesis of a four coordinate iron(ii) complex†

Ismael Nieto,a   Francisco Cervantes-Leeb  and  Jeremy M. Smith*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, USA
E-mail: jesmith@nmsu.edu
Fax: +1-505-496-2649
Tel: +1-505-646-3346

b Department of Chemistry, University of Texas at El Paso, El Paso, USA

Abstract

A bulky tripodal tris(carbene)borate ligand, prepared from 1-tert-butylimidazole, is cleanly transferred to iron(II) by a magnesium reagent.

Graphical abstract: A new synthetic route to bulky “second generation” tris(imidazol-2-ylidene)borate ligands: synthesis of a four coordinate iron(ii) complex

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Article information

DOI
https://doi.org/10.1039/B505985B
Article type
Communication
Submitted
27 Apr 2005
Accepted
02 Jun 2005
First published
28 Jun 2005

Chem. Commun., 2005, 3811-3813

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A new synthetic route to bulky “second generation” tris(imidazol-2-ylidene)borate ligands: synthesis of a four coordinate iron(II) complex

I. Nieto, F. Cervantes-Lee and J. M. Smith, Chem. Commun., 2005, 3811 DOI: 10.1039/B505985B

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