Issue 40, 2005
From the journal:

Chemical Communications

Synthesis, structure and magnetic properties of a decametallic Ni single-molecule magnet

Guillem Aromí,a   Simon Parsons,b   Wolfgang Wernsdorfer,c   Euan K. Brechin*b  and  Eric J. L. McInnes*d  

* Corresponding authors

a Departament de Química Inorgànica, Facultat de Química, Universitat de Barcelona, Diagonal 647, E-08028 Barcelona, Spain

b School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, UK
E-mail: ebrechin@staffmail.ed.ac.uk
Tel: +44 (0)131-650-7545

c Laboratoire Louis Néel-CNRS, Cedex 9, 38042 Grenoble, France

d School of Chemistry, The Unversity of Manchester, Oxford Road, Manchester, UK
E-mail: eric.mcinnes@manchester.ac.uk

Abstract

Ferromagnetic exchange between the ten Ni2+ ions in the complex [Ni10(tmp)2(N3)8(acac)6(MeOH)6] leads to a spin ground state of S = 10; single crystal Mvs. H studies reveal the temperature and sweep rate dependent hysteresis loops expected for a single-molecule magnet.

Graphical abstract: Synthesis, structure and magnetic properties of a decametallic Ni single-molecule magnet

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B510097F
Article type
Communication
Submitted
15 Jul 2005
Accepted
17 Aug 2005
First published
13 Sep 2005

Chem. Commun., 2005, 5038-5040

Permissions

Request permissions

Synthesis, structure and magnetic properties of a decametallic Ni single-molecule magnet

G. Aromí, S. Parsons, W. Wernsdorfer, E. K. Brechin and E. J. L. McInnes, Chem. Commun., 2005, 5038 DOI: 10.1039/B510097F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements