Issue 35, 2006

On the electronic structure of the hydrogenase H-cluster

Abstract

X-ray absorption spectroscopic measurements and density functional calculations suggest that the hydrogenase H-cluster is best described as an electronically inseparable 6Fe-cluster due to extensive delocalization of frontier molecular orbitals of the iron centres, sulfide and the non-innocent dithiolate ligands.

Graphical abstract: On the electronic structure of the hydrogenase H-cluster

Supplementary files

Article information

Article type
Communication
Submitted
07 Apr 2006
Accepted
28 Jun 2006
First published
31 Jul 2006

Chem. Commun., 2006, 3696-3698

On the electronic structure of the hydrogenase H-cluster

D. E. Schwab, C. Tard, E. Brecht, J. W. Peters, C. J. Pickett and R. K. Szilagyi, Chem. Commun., 2006, 3696 DOI: 10.1039/B604994J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements