Encapsulation of a guest molecule in a strained form: an extended 36-membered dodecanuclear manganese metallamacrocycle that accommodates a cyclooctane in the S4 symmetry conformation

Rohith P. John; Jaejoon Park; Dohyun Moon; Kyungjin Lee; Myoung Soo Lah

doi:10.1039/B607675K

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Encapsulation of a guest molecule in a strained form: an extended 36-membered dodecanuclear manganese metallamacrocycle that accommodates a cyclooctane in the S₄ symmetry conformation†

Rohith P. John,^a Jaejoon Park,^a Dohyun Moon,^a Kyungjin Lee^a and Myoung Soo Lah*^a

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* Corresponding authors

^a Department of Chemistry and Applied Chemistry, Hanyang University, Ansan, Kyunggi-do
E-mail: mslah@hanyang.ac.kr
Fax: +82 31 407 3863
Tel: +82 31 400 5496

Abstract

An extended 36-membered dodecanuclear manganese metallamacrocycle with S₁₂ symmetry has been synthesized using the ligand N-cyclohexanoylsalicylhydrazide (H₃chxshz) by a self-assembly that accommodates a cyclooctane of conformationally strained S₄ symmetry in its hydrophobic cavity.

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Article information

DOI: https://doi.org/10.1039/B607675K
Article type: Communication
Submitted: 31 May 2006
Accepted: 11 Jul 2006
First published: 31 Jul 2006

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Chem. Commun., 2006, 3699-3701

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Encapsulation of a guest molecule in a strained form: an extended 36-membered dodecanuclear manganese metallamacrocycle that accommodates a cyclooctane in the S₄ symmetry conformation

R. P. John, J. Park, D. Moon, K. Lee and M. S. Lah, Chem. Commun., 2006, 3699 DOI: 10.1039/B607675K

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Chemical Communications