Issue 30, 2007
From the journal:

Dalton Transactions

Synthesis and X-ray structures of water-soluble tris(hydroxymethyl)phosphine complexes of rhodium(i)†‡

Fabio Lorenzini,a   Brian O. Patricka  and  Brian R. James*a  

* Corresponding authors

a Department of Chemistry, The University of British Columbia, Vancouver, B. C., Canada
E-mail: brj@chem.ubc.ca
Fax: +1 604-822-2847
Tel: +1 604-822-6645

Abstract

The water-soluble RhI–THP complexes: RhCl(1,5-cod)(THP) (1), [Rh(1,5-cod)(THP)2]Cl (2), RhCl(THP)4 (3), and trans-RhCl(CO)(THP)2 (4) have been synthesized and characterized, where THP = P(CH2OH)3; 1–3 are the first potentially useful entries into RhI–THP chemistry, while 1 and 4 are the first structurally characterized RhI–THP complexes.

Graphical abstract: Synthesis and X-ray structures of water-soluble tris(hydroxymethyl)phosphine complexes of rhodium(i)

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Article information

DOI
https://doi.org/10.1039/B706691K
Article type
Communication
Submitted
03 May 2007
Accepted
14 Jun 2007
First published
25 Jun 2007

Dalton Trans., 2007, 3224-3226

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Synthesis and X-ray structures of water-soluble tris(hydroxymethyl)phosphine complexes of rhodium(I)

F. Lorenzini, B. O. Patrick and B. R. James, Dalton Trans., 2007, 3224 DOI: 10.1039/B706691K

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