[VIV15SbIII6O42]6−: An antimony analogue of the molecular magnet [V15As6O42(H2O)]6−

Ragnar Kiebach; Christian Näther; Paul Kögerler; Wolfgang Bensch

doi:10.1039/B708744F

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[V^IV₁₅Sb^III₆O₄₂]⁶⁻: An antimony analogue of the molecular magnet [V₁₅As₆O₄₂(H₂O)]⁶⁻†‡

Ragnar Kiebach,^a Christian Näther,^a Paul Kögerler^b and Wolfgang Bensch*^a

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* Corresponding authors

^a Christian-Albrechts-Universität zu Kiel, Institut für Anorganische Chemie, Kiel, Germany
E-mail: wbensch@ac.uni-kiel.de
Fax: +49 431 880 1520
Tel: +49 431 880 2091

^b RWTH Aachen, Institut für Anorganische Chemie, Aachen, Germany

Abstract

A hydrothermal approach employing an amine as reducing agent enables synthesis of an analogue of the arsenato(III)-oxovanadate {V₁₅As₆}, representing the first systematic variation of this intensely studied magnetic system.

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Article information

DOI: https://doi.org/10.1039/B708744F
Article type: Communication
Submitted: 08 Jun 2007
Accepted: 18 Jun 2007
First published: 06 Jul 2007

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Dalton Trans., 2007, 3221-3223

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[V^IV₁₅Sb^III₆O₄₂]⁶⁻: An antimony analogue of the molecular magnet [V₁₅As₆O₄₂(H₂O)]⁶⁻

R. Kiebach, C. Näther, P. Kögerler and W. Bensch, Dalton Trans., 2007, 3221 DOI: 10.1039/B708744F

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Dalton Transactions