Issue 23, 2009
From the journal:

Chemical Communications

Mechanistic insights into a copper–disulfide interaction in oxidation of imines by disulfides†

Jiri Srogl,*a   Jakub Hývl,a   Ágnes Révészb  and  Detlef Schröder*a  

* Corresponding authors

a Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nám. 2, 166 10 Praha 6
E-mail: jsrogl@uochb.cas.cz, detlef.schroeder@uochb.cas.cz
Fax: +420 220183578
Tel: +420 739680642

b Department of General and Inorganic Chemistry, Eötvös Loránd University, Pázmány Péter sétány 1/a, 1117 Budapest, Hungary

Abstract

The concept of using disulfides as an oxidant for Cu(I) is introduced as part of a Cu-catalyzed process leading to the formation of benzothiazole from an iminodisulfide under an inert atmosphere.

Graphical abstract: Mechanistic insights into a copper–disulfide interaction in oxidation of imines by disulfides

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Article information

DOI
https://doi.org/10.1039/B904403E
Article type
Communication
Submitted
04 Mar 2009
Accepted
03 Apr 2009
First published
05 May 2009

Chem. Commun., 2009, 3463-3465

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Mechanistic insights into a copper–disulfide interaction in oxidation of imines by disulfides

J. Srogl, J. Hývl, Á. Révész and D. Schröder, Chem. Commun., 2009, 3463 DOI: 10.1039/B904403E

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