Issue 34, 2009

Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction

Abstract

This study describes a heteroligated, hemilabile PtII–P,S tweezer coordination complex that combines a chiral Jacobsen–Katsuki MnIII-salen epoxidation catalyst with an amidopyridine receptor, which leads to an inversion of the major epoxide product compared to catalysts without a recognition group.

Graphical abstract: Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction

Supplementary files

Article information

Article type
Communication
Submitted
05 May 2009
Accepted
25 Jun 2009
First published
16 Jul 2009

Chem. Commun., 2009, 5121-5123

Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction

P. A. Ulmann, A. B. Braunschweig, O. Lee, M. J. Wiester, G. C. Schatz and C. A. Mirkin, Chem. Commun., 2009, 5121 DOI: 10.1039/B908852K

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