Issue 37, 2009
From the journal:

Chemical Communications

Two diamino-substituted lithiocarbanions in one molecule†

Ina Kamps,a   Andreas Mix,a   Raphael J. F. Berger,a   Beate Neumann,a   Hans-Georg Stammlera  and  Norbert W. Mitzel*a  

* Corresponding authors

a Lehrstuhl für Anorganische Chemie und Strukturchemie, Universität Bielefeld, Universitätsstraße 15, 33615 Bielefeld, Germany
E-mail: mitzel@uni-bielefeld.de
Fax: +49 521 106 6026

Abstract

tert-Butyllithium deprotonates bis(3-methyl-1,3-diazacyclohex-1-yl)methane and its five-ring analogue regioselectively at both endocyclic NCH2N units; a deprotonation intermediate has been isolated and structurally characterised.

Graphical abstract: Two diamino-substituted lithiocarbanions in one molecule

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Article information

DOI
https://doi.org/10.1039/B909561F
Article type
Communication
Submitted
14 May 2009
Accepted
23 Jul 2009
First published
20 Aug 2009

Chem. Commun., 2009, 5558-5560

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Two diamino-substituted lithiocarbanions in one molecule

I. Kamps, A. Mix, R. J. F. Berger, B. Neumann, H. Stammler and N. W. Mitzel, Chem. Commun., 2009, 5558 DOI: 10.1039/B909561F

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