Issue 37, 2009
From the journal:

Chemical Communications

Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine†

Margarita Paneque,a   Manuel L. Poveda,*a   Florencia Vattier,a   Eleuterio Alvareza  and  Ernesto Carmona*a  

* Corresponding authors

a Instituto de Investigaciones Químicas, Departamento de Química Inorgánica, Consejo Superior de Investigaciones Científicas, Universidad de Sevilla, Avda. Américo Vespucio 49Isla de la Cartuja, Sevilla, Spain
E-mail: guzman@us.es
Fax: +34 95-446-0565
Tel: +34 954-489-558

Abstract

Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex 2 and binuclear 3, in which the polypyridine behaves, respectively, as a mono- or a bi-dentate N-heterocyclic carbene.

Graphical abstract: Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine

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Article information

DOI
https://doi.org/10.1039/B909837B
Article type
Communication
Submitted
18 May 2009
Accepted
03 Aug 2009
First published
18 Aug 2009

Chem. Commun., 2009, 5561-5563

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Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine

M. Paneque, M. L. Poveda, F. Vattier, E. Alvarez and E. Carmona, Chem. Commun., 2009, 5561 DOI: 10.1039/B909837B

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