Issue 47, 2009

Aryloxide anions can form outer sphere complexes with metals as electropositive as uranium

Abstract

A uranium complex containing an outer sphere aryloxide anion is formed by the proteolytic cleavage of the methyl group in the mono-methyl uranium metallocene, (C5Me5)2[iPrNC(Me)NiPr]UMe, by 2,6-di-tert-butyl-4-methyl phenol.

Graphical abstract: Aryloxide anions can form outer sphere complexes with metals as electropositive as uranium

Article information

Article type
Communication
Submitted
22 Jun 2009
Accepted
20 Oct 2009
First published
05 Nov 2009

Chem. Commun., 2009, 7342-7344

Aryloxide anions can form outer sphere complexes with metals as electropositive as uranium

W. J. Evans, J. R. Walensky and J. W. Ziller, Chem. Commun., 2009, 7342 DOI: 10.1039/B912222B

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