Issue 47, 2009
From the journal:

Chemical Communications

Ni-catalyzed regioselective three-component coupling of alkyl halides, arylalkynes, or enynes with R–M (M = MgX′, ZnX′)†

Jun Terao,*a   Fumiaki Bandob  and  Nobuaki Kambe*b  

* Corresponding authors

a Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan
E-mail: terao@scl.kyoto-u.ac.jp
Fax: +81-75-383-2516
Tel: +81-75-383-2514

b Department of Applied Chemistry Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871, Japan
E-mail: kambe@chem.eng.osaka-u.ac.jp
Tel: +81-6-6879-7388

Abstract

A new method for the regioselective three-component cross-coupling of alkyl halides, alkynes, or enynes with organomagnesium or organozinc reagents in the presence of a nickel catalyst and a dppb ligand has been developed.

Graphical abstract: Ni-catalyzed regioselective three-component coupling of alkyl halides, arylalkynes, or enynes with R–M (M = MgX′, ZnX′)

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Article information

DOI
https://doi.org/10.1039/B918548H
Article type
Communication
Submitted
08 Sep 2009
Accepted
22 Sep 2009
First published
13 Oct 2009

Chem. Commun., 2009, 7336-7338

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Ni-catalyzed regioselective three-component coupling of alkyl halides, arylalkynes, or enynes with R–M (M = MgX′, ZnX′)

J. Terao, F. Bando and N. Kambe, Chem. Commun., 2009, 7336 DOI: 10.1039/B918548H

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